 | Hites, R. H. and Raff J. D. Elements of Environmental Chemistry, 2012, 2nd ed. John Wiley & Sons, Hoboken, NJ, pp. 339 |
Publications
Journal Articles
 | Mushinski, R. M.; Phillips, Richard P.; Payne, Z. C.; Abney, R. B.; Jo, I.; Fei, S.; Pusede, S. E.; White, J. R.; Rusch, D.; Raff, J. D. "Microbial mechanisms and ecosystem flux estimation for aerobic NOy emissions from deciduous forest soils,"Proc. Natl. Acad. Sci. USA 2019, 116 (3), 2138-2145. DOI: 10.1073/pnas.1814632116 |
 | Alwe, H. D.; Millet, D. B.; Chen, X.; Raff, J. D.; Payne, Z. C.; Fledderman, K. "Oxidation of Volatile Organic Compounds as the Major Source of Formic Acid in a Mixed Forest Canopy,"Geophysical Research Letters 2019, 46, 2940-2948. DOI: 10.1029/2018GL081526 |
 | Lambe, A. T.; Krechmer, J. E.; Peng, Z.; Casar, J. R.; Carrasquillo, A. J.; Raff, J. D.; Jimenez, J. L.; Worsnop, D. R. "HOx and NOx production in oxidation flow reactors via photolysis of isopropyl nitrite, isopropyl nitrite-d7, and 1,3-propyl dinitrite at λ = 254, 350, and 369 nm,"Atmos. Meas. Tech. 2019, 12, 299-311. DOI: 10.5194/amt-12-299-2019 |
 | Beckett, D., Edelmann, M., Raff, J.D., Raghavachari, K. "Hidden complexities in the reaction of H2O2 and HNO revealed by ab initio quantum chemical investigations," Phys. Chem. Chem. Phys. 2017, 19, 29549–29560.DOI: 10.1039/C7CP05883G |
 | Scharko, N. K., Martin, E. T., Losovyj, Y., Peters, D. G., Raff, J. D. "Evidence for Quinone Redox Chemistry Mediating Daytime and Nighttime NO2-to-HONO Conversion on Soil Surfaces," Environ. Sci. Technol. 2017, 51, 9633–9645. DOI: 10.1021/acs.est.7b01363 |
 | Kebede, M. A., Bish, D. L., Losovyj, Y., Engelhard, M. H., Raff, J. D. "The Role of Iron-Bearing Minerals in NO2 to HONO Conversion on Soil Surfaces" Environ. Sci. Technol. 2016, 50, 8649–8660. DOI: 10.1021/acs.est.6b01915 |
 | Scharko, N. K., Schuette, U. M. E., Berke, A. E., Banina, L., Peel, H. R., Donaldson, M. A., Hemmerich, C., White, J. R., Raff, J. D. "Combined Flux Chamber and Genomics Approach Links Nitrous Acid Emissions to Ammonia Oxidizing Bacteria and Archaea in Urban and Agricultural Soil,"Environ. Sci. Technol. 2015, 49, 13825–13834.DOI: 10.1021/acs.est.5b00838 |
 | Raff, J. D. "Night-time sinks, daytime sources,"Nature Geosci. 2015, 8, 5–6. [invited commentary] |
 | Donaldson, M. A., Bish, D. L., Raff, J. D. "Soil Surface Acidity Plays a Determining Role in the Atmospheric-Terrestrial Exchange of Nitrous Acid,"Proc. Natl. Acad. Sci. USA, 2014, 111, 18472–18477 |
 | Scharko, N. K., Berke, A. E., Raff, J. D. "Release of Nitrous Acid and Nitrogen Dioxide from Nitrate Photolysis in Acidic Aqueous Solutions,"Environ. Sci. Technol. 2014, 48, 11991–12001 |
 | Donaldson, M. A., Berke, A. E., Raff, J. D. "Uptake of Gas Phase Nitrous Acid onto Boundary Layer Soil Surfaces,"Environ. Sci. Technol. 2014, 48, 375–383. |
Kebede, M. A., Scharko, N. K., Appelt, L. E., Raff, J. D. "Formation of Nitrous Acid During Ammonia Photooxidation on TiO2 under Atmospherically Relevant Conditions," J. Phys. Chem. Lett. 2013, 4, 2618–2623 | |
Kebede, M. A., Varner, M. E., Scharko, N. K., Gerber, R. B., Raff, J. D. "Photooxidation of Ammonia on TiO2 as a Source of NO and NO2 under Atmospheric Conditions," J. Amer. Chem. Soc. 2013, 135, 8606–8615 | |
Moussa, S. G., Stern, A. C., Raff, J. D., Dilbeck, D. J., Tobias, D. J., Finlayson-Pitts, B. J. "Experimental and Theoretical Studies of the Interaction of Gas Phase Nitric Acid and Water with a Self-Assembled Monolayer," Phys. Chem. Chem. Phys. 2013, 15, 448–458 [cover] | |
Raff, J. D., Szanyi, J., Finlayson-Pitts, B. J. "Thermal and Photochemical Oxidation of Self-Assembled Monolayers on Alumina Particles Exposed to Nitrogen Dioxide,"Phys. Chem. Chem. Phys. 2011, 13, 604–611 | |
Raff, J. D., Finlayson-Pitts, B. J. "Hydroxyl Radical Quantum Yields from Isopropyl Nitrite Photolysis in Air,"Environ. Sci. Technol. 2010, 44, 8150–8155 | |
Njegic, B., Raff, J. D., Gordon, M., Finlayson-Pitts, B. J., Gerber, R. B. "A Catalytic Role for Water in Atmospheric Production of ClNO,"J. Phys. Chem. A 2010, 114, 4609–4618 | |
Raff, J. D., Njegic, B., Chang, W., Dabdub, D., Gerber, R. B., Gordon, M., Finlayson-Pitts, B. J. "Chlorine Activation Indoors and Outdoors via Surface-Mediated Reactions of Nitrogen Oxides with Hydrogen Chloride,"Proc. Natl. Acad. Sci. USA 2009, 106, 13647–13654 [cover] | |
Kamboures, M. A., Raff, J. D., Miller, Y., Phillips, L. F., Finlayson-Pitts, B. J., Gerber, R. B. "Complexes of HNO3 and NO3ˉ with NO2 and N2O4, and Their Potential Role in Atmospheric HONO Formation," Phys. Chem. Chem. Phys. 2008, 39, 6019–6032 | |
Raff, J. D., Hites, R. A. "Atmospheric Chemistry of Polybrominated Diphenyl Ether Flame Retardants: The Importance of Photolysis as a Fate Process," Environ. Sci. Technol. 2007, 41, 6725–6731 | |
Raff, J. D., Hites, R. A. "Gas-Phase Reactions of Brominated Diphenyl Ethers with OH Radicals,"J. Phys. Chem. A 2006, 110, 10783–10792 | |
Raff, J. D., Stevens, P. S.; Hites, R. A. "Relative Rate and Product Studies of the OH-Acetone Reaction,"J. Phys. Chem. A 2005, 109, 4728–4735 | |
Raff, J. D., Hites, R. A. "Transport of Sediment-Bound Toxaphene in the Mississippi River,"Environ. Sci. Technol. 2004, 38, 2785–2791 | |
Pappenfus, T. M., Raff, J. D., Hukkanen, E. J., Burney, J. R., Casado, J., Drew, S. M., Miller, L. L., Mann, K. R. "Dinitro and Quinodimethane Derivatives of Terthiophene That Can Be Both Oxidized and Reduced. Crystal Structures, Spectra, and a Method for Analyzing Quinoid Contributions to Structure,"J. Org. Chem. 2002, 67, 6015–6024 | |
Pappenfus, T. M., Chesterfield, R. J., Frisbie, C. D., Mann, K. R., Casado, J., Raff, J. D., Miller, L. L. "A pi-Stacking Terthiophene-Based Quinodimethane Is an n-Channel Conductor in a Thin Film Transistor,"J. Am. Chem. Soc. 2002, 124, 4184–4185 | |